Hydrolytic Hydrogenation of Cellulose with the Use of the Ru-containing Polymeric Catalysts

Authors: , , , , , , , ,

Abstract: The study presents the results of cellulose hydrolytic hydrogenation process in subcritical water in the presence of Ru-containing catalysts based on hypercrosslinked polystyrene (HPS) MN-270 and its functionalized analogues: $$NH_{2}-HPS (MN-100) $$ and $$SO_{3}H-HPS (MN-500)$$. It was shown that the replacement of the traditional support (carbon) by HPS increases the yield of the main cellulose conversion products – polyols – important intermediates for the chemical industry. The catalysts were characterized using transmission electron microscopy (TEM), high resolution TEM, and porosity measurements. Catalytic studies demonstrated that the catalyst containing 1.0% Ru and based on MN-270 is the most active. The total yield of sorbitol and mannitol was 50% on the average at 85% cellulose conversion.

Molecular Sciences and Applications, ISSN / E-ISSN: 2944-9138 / 2732-9992, Volume 1, 2021, Art. #7

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V. G. Matveeva, O. V. Manaenkov, A. E. Filatova, O. V. Kislitza, V. Yu. Doluda, E. V. Rebrov, E. M. Sulman, A. I. Sidorov, A. S. Torozova, "Hydrolytic Hydrogenation of Cellulose with the Use of the Ru-containing Polymeric Catalysts," Molecular Sciences and Applications, vol. 1, pp. 35-41, 2021, DOI:10.37394/232023.2021.1.7
V. G. Matveeva, O. V. Manaenkov, A. E. Filatova, O. V. Kislitza, V. Yu. Doluda, E. V. Rebrov, E. M. Sulman, A. I. Sidorov, A. S. Torozova. Hydrolytic Hydrogenation of Cellulose with the Use of the Ru-containing Polymeric Catalysts. Molecular Sciences and Applications. 2021;1:35-41. 10.37394/232023.2021.1.7
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