Conversion of Cellulose with the Use of Catalysts Based on Hypercrosslinked Polystyrene

Authors: , , , , , , , ,

Abstract: The study presents the results of cellulose hydrolytic hydrogenation process in subcritical water in the presence of Ni, Fe, Pt, Pd, Au and Ru-containing catalysts based on hypercrosslinked polystyrene (HPS) MN-270 and its functionalized analogues: NH2-HPS (MN-100) and SO3H-HPS (MN-500). Nonfunctionalized HPS was shown to be the optimal carrier for these catalysts, and Ru-containing catalysts are the most active in the process of cellulose conversion into polyols. In this case the total yield of sorbitol and mannitol was 50% on the average at 85% cellulose conversion. On the basis of the experimental and computed data the pathway of hydrolytic hydrogenation of cellulose was suggested.

WSEAS Transactions on Environment and Development, ISSN / E-ISSN: 1790-5079 / 2224-3496, Volume 12, 2016, Art. #14

PDF
XML
Cite
×
Citation Tools
WSEAS AMA
V. G. Matveeva, O. V. Manaenkov, A. E. Filatova, O. V. Kislitza, V. Yu. Doluda, E. V. Rebrov, E. M. Sulman, A. I. Sidorov, A. S. Torozova, "Conversion of Cellulose with the Use of Catalysts Based on Hypercrosslinked Polystyrene," WSEAS Transactions on Environment and Development, vol. 12, pp. 133-140, 2016, DOI:
V. G. Matveeva, O. V. Manaenkov, A. E. Filatova, O. V. Kislitza, V. Yu. Doluda, E. V. Rebrov, E. M. Sulman, A. I. Sidorov, A. S. Torozova. Conversion of Cellulose with the Use of Catalysts Based on Hypercrosslinked Polystyrene. WSEAS Transactions on Environment and Development. 2016;12:133-140.
Copy to Clipboard
Citation copied to Clipboard

Certification

---