
- Railroad ties.
- Truck bed liners.
- Plastic roads.
The chemical recycling consists in the following
steps:
Step 1) Chemical depolymerization: it is a chemical
process by which the plastic waste is chemically
reduced to its original monomers or other chemicals.
It is suitable only for homogenous pre-sorted plastic
waste streams such as PET, PU, PA, PLA, PC, PHA,
and PEF. Chemical recycling can be done by
chemolysis, pyrolysis, fluid catalytic cracking
(FCC), hydrogen technologies, Katalytische
Drucklose Verölung (KDV) process or Catalytic
Pressureless Depolymerization process, and
gasification combined with methanol production.
Step 2) Solvent-based regeneration: it is a
purification process based on dissolving polymers in
proprietary solvents, separating contaminants and
reconstituting the target polymer. The process can be
applied to several polymers.
Step 3) Thermal depolymerization and cracking
(gasification and pyrolysis): These processes heat
plastic waste in a low-oxygen environment to
produce molecules from mixed streams of
monomers that then form the basis of feedstock for
new plastic without degradation. The main output is
syngas or synthesis gas, [16]. Both gasification and
pyrolysis have been considered for decades to create
energy (syngas burned to drive steam turbines) from
municipal waste that didn’t get a commercial
success due to a combination of poor economics,
high energy consumption requiring supplemental
fuel, fires, explosions, emissions, and residues.
These processes are also used to create ‘plastic to
fuels’ (fossil fuels), as oils and diesel can be
generated in addition to syngas. Most recently
biotechnology has been considered for plastic
degradation and waste management, thus the
depolymerization using enzymes, or bacteria is a
technique still at an experimental and research stage.
One if the studied techniques for example uses a
bacterial hydrolase enzyme to reduce PET to its
monomer, [17]. The bacterial enzyme is based on a
naturally occurring bacteria that has subsequently
been modified by scientists to degrade PET more
efficiently, claiming a 90% depolymerization within
10 hours. More and more examples of use of
enzymes, bacteria but even worms, insects and
larvae for degradation of plastic can be found in the
literature evidencing the trend for looking to natural,
green chemistry, biotechnological approaches for
the plastic waste treatment.
The last approach, we address is valorizing the
plastic waste for energy recovery, this is conducted
by burning plastic waste for electricity production,
this process reports an efficiency above 90%, [18].
The process is proposed for plastic waste that cannot
be recycled, but considering the need for energy is
widely applied even to recyclable plastic. Main
concern for incineration is the management of ashes
and air emissions making it difficult to get
population acceptance of an incineration plant
nearby. Most recent treatments consider the
transformation of plastic to fuels that might
‘substitute’ fossil fuels and offset oil, gas, and coal.
By the way the process still needs investigation and
upgrades, not to result in just compressed post
consuming plastic. One promising approach of this
process is the conversion of plastic waste to
hydrogen, which is a clean burning fuel. However,
to date, hydrogen production may require energy-
intensive processes that could even compromise the
benefits of reducing the carbon footprint.
3.1 Logistic and distribution solutions
Solutions must be studied starting from the entire
plastic waste production chain and researching how
each node in the supply chain can give its own help
to solve the problem. For example, industries are
expected to work together by creating and
implementing a plastic waste management system
using a reverse logistics system where plastic waste
is returned to the factories that produce it.
Afterwards, factories will manage the plastic waste
by recycling and reusing them. Reverse logistics is
the process of planning, implementing, and
controlling the flow of raw materials, work in
process, finished goods, and related information,
which flows from the point of consumption to the
point of origin efficiently, [19]. Logistics generally
bring products to customers.
Reverse logistics is the opposite of the previous
process, where the product or goods are brought
from the customer to the distributor, or to the
manufacturer, which includes reprocessing or
disposal. The transfer of the product or item is
carried out through a supply chain network, like the
one shown in previous Fig. 2. Another way to
manage plastic waste is to optimize the plastics
packaging supply chain. The plastics packaging
value chain starts along with the production and
continues with the distribution and utilization. On
the left side, indeed, there is the Plastics Packaging
Recovering Chain i.e., the packaging producers, the
product companies, and the retailers who produce
the packaging, the products and sell them to the
International Journal of Environmental Engineering and Development
DOI: 10.37394/232033.2023.1.20
Antonio Pratelli, Patrizia Cinelli,
Maurizia Seggiani, Giovanna Strangis,
Massimiliano Petri