Optimizing Red Soil-Based Geopolymer Bricks:
A Sustainable Approach towards Environmentally Friendly
Construction Materials
SHIVARAJU GD1,2,*, ASHA K.1
1Department of Civil Engineering,
BMS College of Engineering,
Bangalore, Karnataka, 560019,
INDIA
2Department of Civil Engineering,
Sri Siddhartha Institute of Technology, SSAHE,
Tumakuru, Karnataka,
INDIA
*Corresponding Author
Abstract - In the whole world, construction activities are happening rapidly as a result of the population
increase and also due to the lifestyle of people in the 20th century, intensifying the pressure on resources
needed for construction. It also causes bad effects on the environment, such as the carbon footprint associated
with cement production and the waste management of emission waste like fly ash in thermal power plants.
Counteracting and stabilizing the adverse environmental consequences, this study adopts an experimental
approach to utilize thermal power plant waste Class C Fly ash (pozzolanic), locally available red soil, and stone
dust, along with geopolymer precursors, to manufacture bricks, which are the most demanding material for
infill masonry work. The mechanical, durability, and microstructural characterization of the bricks were studied
for various mix proportions, along with various concentrations of geopolymer precursors, cured at elevated
temperatures and ambient curing. An optimum methodology was obtained to develop a red soil-based
geopolymer brick.
Key-Words: - Red Soil, Fly Ash, Stone Dust, Geopolymer brick, pozzolanic, microstructural characterization.
Received: May 29, 2023. Revised: February 19, 2024. Accepted: March 13, 2024. Published: May 2, 2024.
1 Introduction
In the present scenario, the utility of concrete across
the globe is placed in the second position next to
water. As of date, only cement is predominantly used
as a principal binder to produce concrete. However,
environmental concerns associated with the
production of cement are seriously viewed, [1].
Production of one ton of cement releases almost one
ton of carbon dioxide (CO2 Due to a rapid increase in
the infrastructure sector, the production of cement
leads to acute depletion of non-renewable resources
like natural lime rock, coal, etc, [2]. The hydration of
cement which is an exothermic reaction emits a huge
amount of heat energy thereby increasing the
atmospheric temperature. On the other hand, CO2 is
the prime greenhouse gas and it contributes
significantly to environmental pollution and ozone
depletion. Based on the above factors, enormous
efforts have been made to minimize cement usage
and invent an eco-friendly alternative binder, [3].
The amply stockpiled fly ash from thermal
power plants posed a nuisance at its disposal.
However, the fly ash exhibited excellent
cementitious properties and showed a potential
replacement for cement, [4]. This has sparked the
idea of involving fly ash in the cement and concrete
manufacturing process. The physical and chemical
properties of fly ash also confirmed its possible
utility in concrete by replacing cement partially or
completely, [5].
Geopolymers are acknowledged as a potential
alternative binder to OPC, for decreasing carbon
dioxide emissions and accomplishing effective waste
recycling. This cement-free geopolymer composite is
budding as an exceptionally sustainable building
material, [6]. Despite these advantages over Portland
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Cement Concrete (PCC), Geo Polymer Concrete
(GPC) possesses certain limitations in its application
due to the lack of knowledge in its microstructure
formation and non-standardized mix design
procedures. Because of this knowledge gap,
researchers tend to formulate, mix proportions, and
adapt their manufacturing practices, [7]. The
parameters involved in the synthesis of geopolymer
composites are highly sensitive. They depend on the
physical, chemical, and mineralogical compositions
of constituents such as aggregates, fly ash, water,
NaOH, and Na2SiO3 solutions. Also, the prevailing
temperature during solution preparation, mixing,
casting, and curing phases influences the parameters,
[8]. Moreover, the need for elevated temperature
curing has also confined their usage in precast
applications. The use of low calcium content fly ash-
based geopolymer concrete mandatorily requires
curing by elevated temperature for the effective
polymerization process, [9]. Hence, an effective
breakthrough is essential for expanding the use of
GPC in different applications. If the fly ash-based
geopolymer concrete could be developed with an
appropriate mix design, it could demonstrate
enhanced mechanical and chemical properties of
concrete on par with Portland cement concrete, [10].
Latent cementitious materials like Class C Fly Ash
(CFA) and Ground Granulated Blast Furnace Slag
(GGBS) contain adequate calcium to form
cementitious compounds when they interact with
water. The dormant hardening energy becomes active
only under the stimulus of an activator like calcium
hydroxide or strong alkaline such as sodium
hydroxide or potassium hydroxide, [11]. When these
latent cementitious materials are blended with
Portland cement and water, the calcium hydroxide
produced during the hydration of the brick plays the
activator role. This is an exothermic reaction and
emits a significant amount of heat energy. The
evolved heat energy can be utilized for inducing the
polymerization process in a geopolymer brick, [12].
Therefore, this study targets the ambient curing of
geopolymer bricks and their suitability under various
loading conditions in different environmental factors.
2 Literature Survey
The building sector has a big influence on the
environment, hence research into sustainable
building materials is essential. [13], examine the use
of fly ash (FA) geopolymer binder in the
manufacturing of unburned bricks. The goal of the
study is to optimize the ratio between FA and
alkaline activator solution (AAS) in blocks, with
several ratios being examined. Properties including
flexural tensile strength, compressive strength, and
water absorption were measured when the blocks
were tested at room temperature and 60°C. The
analytical methods employed were Fourier
Transform Infrared (FTIR) and Scanning Electron
Microscope (SEM The required quantity of AAS was
8%, however, the results indicated that blocks with
20% AAS had the highest compressive strengths.
The ratio of quasi-dry to saturated compressive
strength was greater than 0.5, in compliance with
current norms.
The environmental impact of red mud and waste
foundry sand is significant, while natural clay for
brick manufacturing is scarce. In a study, [14],
provided a method for using red mud in clay bricks
without pretreatment and calcination to replace
natural clay in bricks using red mud, waste foundry
sand, and fly ash. It utilized a polymeric approach,
avoiding calcination. The bricks with varying
concentrations utilized 12M bricks. To minimize
heavy efflorescence over time, the caustic
concentration was reduced to 5 M using red mud, the
bricks eventually decreased efflorescence providing a
strength of  
. However, this study does
not provide sufficient data on factors such as
weathering effects, resistance to environmental
stresses, and potential degradation over time.
A study, [15], focused on examining the early
ages of precursor-activator suspension structures in
alkali-activated ground granulated blast furnace slag
and fly ash mixtures through mechanical and
chemical evolution. The study found that the setting
time of these mixtures is prolonged and the heat of
hydration decreases with fly ash content. Also found
that weight loss due to hydrate decomposition is
around 30% of weight loss at 28 days, while in the
OPC system, it is less than 10%. The quick setting of
alkali-activated slag mixtures is due to rapid
coagulation and rigidification of the network, while
OPC binders setting is due to a network formed by
partially hydrated or anhydrous cement particles.
As a result of climate change, more people are
using wood pellets as a sustainable energy source;
nevertheless, this increased use results in the
generation of wood pellet fly ash (WA) by-products.
Their study, [16], created wood pellet fly ash blended
binder (WABB), a new sustainable building material
composed of 20% cement, 30% GGBS, and 50%
WA. A battery of experiments is used to evaluate the
material's stabilizing ability in weathered granite soil
(WS The average qu climbed by 1.88 to 11.77 as the
WABB dose rate increased, according to the data,
which is greater than compacted WS without a
binder. It was also established that novel
cementitious minerals exist. The function of cement
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in the early strength development and the latent
hydraulic capabilities of ground granulated blast-
furnace slag (GGBS) are thought to be responsible
for the combined hydration process of WABB.
Cement, which adds to air pollution and
greenhouse gas emissions, might be replaced with
lateritic soils found in Bolivia's wet tropical regions.
The compressive strength, chemical composition,
and mineralogy of geo-polymers derived from
lateritic clays have all been investigated. Research on
Bolivia's lateritic clays and their combined
mechanical, mineralogical, and chemical
characteristics in a geo-polymer, however, is lacking.
The goal of the study, [17], was to assess a geo-
polymer derived from laterite clays. On mortar and
geo-polymer cubes and prisms, compression, and
flexural tests were performed along with
mineralogical and chemical studies. The laterite clay-
based geo-polymer exhibited a marginally higher
flexural strength but a lower compressive strength
when compared to Portland cement IP mortar,
according to the results.
In the study, [18], used the plastic damage model
of Weibull distribution and the energy dissipation
mechanism to investigate the deformation and
damage laws of solidified soils during compression
failure. It looks at how the qualities of the soil are
affected by curing ages, moduli, cement, ground
granulated blast furnace slag (GGBS), and alkali-
activator contents. According to the study, energy
dissipation occurs when a specimen is damaged
under stress, and the dissipation energy ratio (Ud/U)
and damage variable are used to characterize soil
damage. The brittleness index (BI) is determined,
demonstrating that when the modulus and curing age
drop, the BI and Ud/U rise while the dissipation
energy ratio and dissipation energy fall.
3 Materials and Methodology
This research focuses on utilizing deteriorated red
soil, locally available, in Karnataka, in union with
stone dust and fly ash. An alkali solution serves as a
binder to create geopolymer bricks. The mix design,
optimizing the red soil-based geopolymer brick
preparation, involves varying ratios of red soil to
stone dust, with a fixed percentage of fly ash. The
alkali solution is fine-tuned by adjusting molarity
and alkali-to-silicate ratio under different curing
temperatures. The resulting bricks undergo
comprehensive evaluation, considering physical and
durable parameters, alongside a scrutiny of structural
integrity.
3.1 Materials Used
Red Soil, fly ash, Stone Dust, and aluminum silicate
gel as a binder was used in this research to make the
specimen for experimentation. This section in detail
explains the physical and chemical properties of the
materials being utilized.
3.1.1 Red Soil
The locally available red soil is used for this study,
the soil is procured from Tumakuru, Karnataka,
India. The red soil sourced from Tumakuru,
Karnataka, India, exhibits specific physical and
chemical properties.
Table 1. Physical properties of red soil
Physical Properties
Specific gravity
2.62
Neutral pH
7.24
Electrical conductivity
96 μS/cm
Liquid limit
34.12
Plastic limit
34.12
Dry density
1.99 gm/cc
As shown in Table 1, the soil exhibits a specific
gravity of 2.62 and a neutral pH of 7.24, the soil's
electrical conductivity is measured at 96 μS/cm. Its
liquid limit and plastic limit are determined to be
34.12 and 34.12, respectively, while the dry density
stands at 1.99 gm/cc.
Table 2. Chemical composition of red soil
Silicon dioxide (SiO2)
74.23%
Aluminium oxide (Al2O3)
19.07%
Calcium oxide (CaO)
1.2%
Magnesium oxide (MgO)
0.8%
Iron oxide (Fe2O3)
5.9%
Analyzing the chemical composition, the soil
comprises 74.23% silicon dioxide (SiO2), 19.07%
aluminum oxide (Al2O3), 1.2% calcium oxide
(CaO), 0.8% magnesium oxide (MgO), and 5.9%
iron oxide (Fe2O3) as shown in Table 2. These
findings offer a broad thoughtful of the red soil's
characteristics, crucial for measuring its suitability in
various applications, such as construction.
3.1.2 Fly-Ash
Class C Fly ash (pozzolonic) which was acquired
from the Raichur thermal power plant was utilized in
this research to stabilize the red soil.
Table 3. Physical properties of fly ash
Physical Properties
Specific gravity
2.15
Neutral pH
8.4
Electrical conductivity
225 μS/cm
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Karnataka, which was characterized and the
outcomes are tabulated in Table 3, has a Specific
gravity of 2.15, pH 8.4, and Electrical Conductivity
(µS/cm) 225.
Table 4. Chemical composition of fly ash
Chemical Composition
Silicon dioxide (SiO2)
55%
Aluminium oxide (Al2O3)
24%
Calcium oxide (CaO)
0.98%
Magnesium oxide (MgO)
0.47%
Iron oxide (Fe2O3)
7.8%
Potassium oxide (K2O)
1.75%
Titanium oxide (TiO2)
1.45%
Chemical composition SiO2(%) 55, Al2O3(%)
24, CaO (%) 0.98, MgO (%) 0.47, K2O(%) 1.75,
Fe2O3(%) 7.8, TiO2(%) 1.45, Loss on ignition(%)
5.25, as shown in Table 4.
3.1.3 Stone Dust
Stone dust (SD) is a finely crushed material. After
double washing, it is procured from the available
nearby quarry of Tumakuru. Karnataka, India. As per
the unified soil classification system (USCS), the
stone dust may be categorized as mineral sediment
with truncated compressibility. Quarry dust and rock
dust are other names for SD. SD is a by-product
produced by stone crusher operations. The use of
stone dust in concrete can help preserve ordinary
gravel for imminent peers while also improving
concrete quality. It has an SG of 2.67. Table 5 and
Table 6 provides the physical and chemical
composition of quarry dust.
Table 5. Physical properties of quarry dust
Physical Properties
Specific gravity
2.67
Bulk relative density
1820 kg/m3
Absorption
1.55 %
Quarry dust has a specific gravity of 2.67,
significantly greater than water density, and a bulk
relative density of 1820 kg/m3, with a moisture
absorption rate.
Table 6. Chemical composition of quarry dust
Chemical Composition
Silicon dioxide (SiO2)
62.48%
Aluminium oxide (Al2O3)
18.72%
Calcium oxide (CaO)
4.83%
Magnesium oxide (MgO)
2.56%
Iron oxide (Fe2O3)
6.54%
Potassium oxide (K2O)
3.18%
Titanium oxide (TiO2)
1.21%
The chemical composition of quarry dust is
shown in the table, along with the percentages of the
different oxides. The majority, or 62.48%, is made
up of silicon dioxide (SiO2), which is followed by
aluminum oxide (Al2O3), magnesium oxide (MgO),
calcium oxide (CaO), iron oxide (Fe2O3), potassium
oxide (K2O), titanium oxide (TiO2), and magnesium
oxide (MgO) at 18.72%, 4.83%, and 2.56%.
3.1.4 Geopolymer Solution
Geopolymer was created by combining an alumina
silicate source with a strong alkali solution such as
sodium hydroxide (NaOH) or potassium hydroxide
(KOH), which forms an alumina silicate gel that acts
as binding material.
3.1.4.1 Sodium Hydroxide (NaOH)
The physical appearance of sodium hydroxide is in
the form of pellets. Its basic alkali solution has a
molar mass of 39.997 gms/mol, and it's an inorganic
compound, also known as caustic soda, that was
procured in the form of crystalline.
3.1.4.2 Sodium Silicate (Na2SiO3)
It's a silicate solution procured in the form of liquid
which is heavy and also known as water glass.
3.1.5 Potable Water
The potable drinking water available in the locality is
utilized for the development of dilution of sodium
hydroxide to the essential clarification. Tap water
conforming to IS 456 was used to mix brick material.
3.2 Methodology
All necessary materials were acquired, including red
soil, fly ash, stone dust, NaOH, and Na2SiO3, and a
thorough characterization of each material was
conducted to assess their individual properties.
3.2.1 Solution Preparation
With a molarity of 6M NaOH was mixed with
distilled water for at least 24 hours to make a
solution. Na2SiO3 liquid was prior mixed with the
dry materials. Both NaOH solution and NaSiO
were kept to mix in the next process. The hydroxide
solutions with varying molarity, ranging from 6M to
14M, with a 2M increment. Four different ratios of
mixing NaOH with Na2SiO3 were considered in this
research as shown in Table 7.
Table 7. Various NaOH to Na2SiO3 ratios
Ratio
NaOH
Na2SiO3
Ratio -1
1
1
Ratio -2
1
1.5
Ratio -3
1
2.0
Ratio -4
1
2.5
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3.2.2 Dry Mix Preparation
To make a homogenous mixture, binders, and fine
aggregates are mixed one after the other. First, a part
of fly ash (FA) is mixed with a blend of red soil and
stone dust. Then, for three minutes, the mixture is
completely mixed until it has a uniform color.
Table 8. Various Mix ratios
Mix
Red Soil
Stone Dust
Fly Ash
Mix-1
100
0
0
Mix-2
90
0
10
Mix-3
80
10
10
Mix-4
70
20
10
Mix-5
60
30
10
Mix-6
50
40
10
Mix-7
40
30
10
The crush resistance analysis of different mix
ratios (mix-1 to mix-7) combined with a constant
alkali activator ratio 1: 2.5 as shown in Table 8,
cured in an oven for 24 hours at 60°C, to reveal
noteworthy findings.
3.2.3 Wet Mixing
The brick samples were prepared for various mix
ratios and molarities while maintaining a consistent
1:2.5 NaOH to Na2SiO3 ratio. The samples are cured
for 24 hours in an oven at a high temperature of
60°C. The NaOH to Na2SiO3 ratio is adjusted in
increments of 0.5 while maintaining the ideal ratios,
and these specimens are also cured for 24 hours at
60°C. As the ideal values are recognized, specimens
are made and cured at temperatures between 60°C
and 120°C in steps of 10°C. The proper mix ratio,
molarity, NaOH to Na2SiO3 ratio, and oven curing
temperature are determined by analyzing all test data
to make red soil-based geo-polymer bricks.
4 Experimentation
Fig. 1: Red mud-based Geopolymer Bricks
The study makes use of materials from thermal
power plants, quarry dust, and specific geopolymer
ingredients. Red soil's mineral composition and
physical properties were studied, and the chemical
composition and fineness of class C fly ash were
investigated. Stone dust was screened for particle
size distribution and chemical composition.
Geopolymer ingredients, such as activators and
silicates, were chosen for their compatibility with the
red soil and fly ash compositions. Figure 1 represents
the red mud geopolymer bricks. The
brick's resistance to environmental factors and
durability over time is evaluated through mechanical
and durability for strength and flexibility and also for
moisture resistance and resilience in harsh
conditions, which ensure their suitability for
sustainable construction projects.
5 Test Results
This paper identifies the ideal curing conditions,
specimens were cured at various temperatures and
their temperature-dependent behavior was examined.
By performing various tests, the behavior of
geopolymer mixes was studied to obtain better
results by optimizing mix design and curing
processes.
5.1 XRD Analysis
Fig. 2: XRD Image of Red Soil
Fig. 3: XRD image of Fly Ash
The diffraction pattern that results from the XRD
examination shows the composition, crystal
structure, and phase purity of the brick material. As
illustrated in Figure 2 and Figure 3, we can
understand the diffraction characteristics, uses, and
possible applications of red soil and fly ash.
(a)
(b)
(c)
Position [°2Theta]
10 20 30 40 50 60 70 80 90
Counts
0
100
400
900
Q
M
Q
MM
Q
M
QQ
Q
MQQ
PLAINF~1.CAF
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5.2 SEM Analysis
Fig. 4: SEM image of Red Soil and Fly Ash (Class
C)
Scanning Electron Microscopy (SEM) is a
significant way to assess how exposure to sulfate and
various dry and wet cycles impact the internal
structure of the brick specimens. Figure 4, shows the
SEM image of red soil and Fly Ash. Understanding
the mechanical properties, strength, and durability is
made easier with the help of the visual information
provided by the microstructural analysis. The
microstructural behavior of damaged specimens after
exposure to different conditions is depicted in Figure
5 and Figure 6. It aids in identifying defects or
weaknesses in brick structures like voids, cracks, or
poor bonding, thereby optimizing the manufacturing
process and enhancing the quality and performance
of bricks.
R
Ratio -1
Ratio -2
Ratio -3
Ratio -4
600 C
1200 C
Fig. 5: A mix of red-based geopolymer bricks cured at 600 C and 1200 C shows different alkali activator ratios
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After Oven Drying
After water absorption
After wetting & Drying
After Sulphate Attack
Fig. 6: SEM image of brick of 60:10:30 mix proportion at 1: 2.5 alkali activator ratio subjected to various
conditions
It also provides a visual narrative of the
material's response to different conditions,
facilitating a more comprehensive understanding of
its performance and behavior under diverse
environmental challenges. The investigation extends
to mix 5, utilizing an 8M hydroxide solution with a
ratio of 3. Specimens are cast and cured in an oven
for 24 hours at varying elevated temperatures,
ranging from 60°C to 120°C, with increments of
10°C. Crush resistance assessments are conducted on
the specimens, and the results are analyzed.
For the obtained optimum mix ratio of 60:10:30
(Red Soil: Fly Ash: Stone Dust), the study aims to
optimize the NaOH to Na2SiO3 by varying the
NaOH to Na2SiO3 ratio. The investigation spans a
range from 1:1 to 1:2.5, with increments of 0.5. This
systematic variation is designed to identify the ideal
mix ratio that balances the cost considerations while
maintaining desirable properties in the geopolymer
material.
The observed trend in the study reveals that the
strength of the specimens increases proportionally
with a rise in the alkali activator ratio, specifically
from 1:1 to 1:2.5. However, noteworthy insight is
gained by recognizing that the rate of increase
becomes marginal between the ratios of 1:2 and
1:2.5.
5.3 Compressive Strength Analysis of
Various Mix Ratios for Different
Molarities
Fig. 7: Compressive Strength behavior of various
mix ratios for different Molarities
According to Figure 7, mix 5 consistently
demonstrates superior strength across all molarities
studied. The analysis from Graph.1 consistently
highlights the superior performance of mix 5 across
various molarities. Notably, the crush resistance after
alternative dry and wet cycles exhibits a substantial
increase of 22 to 25% compared to the dry
compressive strength after oven curing. This
enhancement is attributed to the removal of leaching
during wetting and drying, contributing to the overall
strength improvement, as observed and documented
by Preethi and Venkatarama Reddy in 2020.
However, it's noteworthy that the strength of the
brick experiences a reduction of 20 to 25% during
both sulfate and chloride resistance tests when
compared to the dry compressive strength. This
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decline is expected due to the challenging
environmental conditions posed by these corrosive
agents. Considering these outcomes, the combination
of an 8M NaOH concentration and mix 5 emerges as
the optimal choice for further studies. This selection
is supported by a robust performance across various
tests and conditions, setting the stage for in-depth
investigations into the specific characteristics and
applications of this geopolymer mix.
5.4 Compressive Strength Results of Various
Alkali Activator Ratio
Fig. 8: Compressive strength results of various Alkali
activator ratio
Based on the previous evaluation and report from
Table 7, 1:2 f NaOH to Na2SiO3 ratio is selected as
optimal and the respective compressive test results
are shown in Figure 8. As a noticeable increase in
compressive strength is seen and all values fall
within the permissible range, this ratio is regarded as
very suitable. Adopting the 1:2 ratio offers an
appropriate balance between improving strength and
ensuring that the geopolymer brick material remains
within permitted performance restrictions. This
optimal ratio is a reasonable proposition in terms of
achieving cost-effectiveness along with efficiency
standards.
5.5 Compressive Strength Results of Various
Oven Curing Temperature
Fig. 9: Compressive strength results of varying oven
curing temperature
Examining the behavior of the geopolymer
material at varying temperatures is crucial to
determining the ideal curing conditions that optimize
the sample’s strength. This understanding improves
the production process and optimizes the curing
parameters for the geopolymer mix, ensuring
efficiency and effectiveness in identifying the
optimum brick specimen. From the Figure 9,
illustrates a distinct trend, indicating that the crush
resistance of the specimens experiences an increase
up to 70°C. Beyond this temperature, there is a
noticeable reduction in strength with further
temperature increases. This observation suggests that
the geopolymer material reaches its optimal strength
at 70°C, and elevated temperatures beyond this point
may induce a decline in compressive strength.
5.6 Sulphate and Chloride Attack Results
based on Mix 5
The investigation was extended to mix 5, utilizing an
8M hydroxide solution with a ratio of 3. Specimens
are cast and cured in an oven for 24 hours at varying
elevated temperatures, ranging from 60°C to 120°C,
with increments of 10°C. Crush resistance
assessments are conducted on the specimens, and the
results are analyzed.
Table 9. Compressive strength in N/mm2 for mix 5
Molarity
Dry
Wet
Alternative
dry and wet
Sulphate
Resistance
Chloride
resistance
6M
4.20
5.65
6.10
3.25
3.65
8M
4.64
5.36
6.48
3.54
3.88
10M
4.90
5.63
6.82
3.67
4.09
12M
4.94
5.69
6.88
3.71
4.13
14M
4.57
5.34
6.02
3.38
3.87
Upon closer examination, Table 9, which
specifically focuses on the crushing strength
behavior of mix 5 for various molarities, highlights
that an 8M molarity of NaOH results in the desired
strength. Notably, a further increase in molarity does
not yield a significant additional enhancement in
compressive strength.
6 Conclusion
In summary, the research findings emphasize the
exceptional performance of Mix-5, characterized by
the mix ratio (60:10:30) and cured at 70 degrees
Celsius. Notably, Mix-5 consistently demonstrates
superior compressive strength across varying
molarities and alkali activator ratios. The
optimization study further discloses that, while
increasing the alkali activator ratio enhances
strength, the rate of improvement becomes marginal
between the ratios of 1:2 and 1:2.5. As a result, a
NaOH to Na2SiO3 ratio of 1:2 is identified as
optimal, striking a steadiness between strengthened
properties and cost-effectiveness. Additionally, the
temperature-dependent behavior of the specimens
indicates that curing at 70 degrees Celsius results in
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peak compressive strength. Beyond this temperature,
there is a noticeable decline in strength. These
insights contribute to the refinement of geopolymer
mix design and curing conditions. The findings of
the research are as follows:
This study was conducted to develop Red Soil-
Based Geopolymer Bricks using industrial
wastes such as fly ash and locally available red
soil which is achieved using different mix ratios.
From the physical and chemical characterization
study, it was concluded that Raichur flash and
locally available soil samples had better chemical
composition suitable for the study.
The microstructural studies conducted using
XRD and SEM analysis indicated the peaks of
mullite (calcium aluminum silicate) and quartz
for fly ash. Sem analysis of fly ash showed a
distinct formation of special hollow cenospheres.
The XRD of red soil showed peaks of quartz,
whereas the SEM of red soil showed aggregation
of soil particles.
The research findings emphasize the exceptional
performance of Mix-5, characterized by the mix
ratio (60:10:30) and cured at 70 degrees Celsius.
Notably, Mix-5 consistently demonstrates
superior compressive strength across varying
molarities and alkali activator ratios.
The optimization study further discloses that,
while increasing the alkali activator ratio
enhances strength, the rate of improvement
becomes marginal between the ratios of 1:2 and
1:2.5. As a result, a NaOH to Na2SiO3 ratio of
1:2 is identified as optimal, striking a steadiness
between strengthened properties and cost-
effectiveness.
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Shivaraju Gd, Asha K.
E-ISSN: 2224-3496
135
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WSEAS TRANSACTIONS on ENVIRONMENT and DEVELOPMENT
DOI: 10.37394/232015.2024.20.14
Shivaraju Gd, Asha K.
E-ISSN: 2224-3496
136
Volume 20, 2024